Tetrabutylammonium perchlorate

四丁基高氯酸铵

What is Tetrabutylammonium perchlorate, cas no:1923-70-2,a producer telling you the result.

                                            CAS NO.1923-70-2

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To begin with, let us tell you what is the basic information ofTetrabutylammonium perchlorate ?

CAS Number

1923-70-2

Molecular Weight

341.914

Molecular Formula

C16H36ClNO4

Melting Point

211-215 °C

Like many stuff, it has many synonyms as follows

MFCD00038722

EINECS 217-655-5

N,N,N-Tributyl-1-butanaminium perchlorate

tetra-n-butylammonium perchlorate

Tetrabutylammonium Perchlorate

tetrabutylammoniumperchlorate

tetra(n-butyl)ammonium perchlorate

1-Butanaminium, N,N,N-tributyl-, perchlorate

Bu4N(1+)*ClO4(1-)

tetrabutylazanium perchlorate

n,n,n-tributylbutan-1-aminium perchlorate

Tetrabutyl ammonium perchlorate

Tetrabutylammonium Perchlorat

[(n-Bu)4N]ClO4

First, the chemical is very special, some technical indexes as below

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Physical property data

1. Appearance: Crystalline

2. Density (g/mL, 25 º C): undetermined

3. Relative vapor density (g/mL, air=1): not determined

4. Melting point (º C): 212

5. Boiling point (º C): undetermined

6. Boiling point (º C, 1mmHg): undetermined

7. Refractive index: undetermined

8. Flash point (° C): undetermined

9. Specific rotation (º F): not determined

10. Spontaneous combustion point or ignition temperature (º C): not determined

11. Vapor pressure (kPa, 25 º C): not determined

12. Saturated vapor pressure (kPa, 110 º C): not determined

13. Combustion heat (KJ/mol): undetermined

14. Critical temperature (º C): not determined

15. Critical pressure (KPa): undetermined

16. Logarithmic value of oil-water (octanol/water) partition coefficient: undetermined

17. Explosion upper limit (%, V/V): undetermined

18. Lower explosive limit (%, V/V): not determined

19. Solubility: Able to dissolve in water

toxicology data

Acute toxicity:

Main irritant effects:

On the skin: irritates the skin and mucous membranes.

Above the eyes: the impact of stimulation.

Sensitization effect: There is no known sensitization effect.

Ecological data

It is slightly harmful to water. Do not let undiluted or large amounts of products come into contact with groundwater, waterways, or sewage systems. Do not discharge materials into the surrounding environment without government permission.

 

Molecular structure data

None

Calculate chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): None

2. Number of hydrogen bond donors: 0

3. Number of hydrogen bond acceptors: 4

4. Number of rotatable chemical bonds: 12

5. Number of tautomers: None

6. Topological molecule polarity surface area 74.3

7. Number of heavy atoms: 22

8. Surface charge: 0

9. Complexity: 212

10. Number of isotopic atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 2

Nature and stability

If used and stored according to specifications, it will not decompose, there are no known hazardous reactions, and oxidation should be avoided

Storage

Keep the storage container sealed and stored in a cool, dry place, ensuring good ventilation or exhaust in the workspace

Second, the Synthetic Route we will recommend is the most important for your reference?

First, synthesis line ofTetrabutylammonium perchlorate CAS NO.1923-70-2  as follows

Synthetic method

There are various methods for preparing tetra-n-butylammonium perchlorate, and the common method is to obtain it by reacting n-butylamine with perchloric acid. The reaction conditions generally require lower temperatures and suitable solvents.

Third, what is the usage of Tetrabutylammonium perchlorate  CAS NO.1923-70-2  pleas see below

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Usage:

Used as a supporting electrolyte

-Tetra-n-butylammonium perchlorate is commonly used as an ionic liquid catalyst in organic synthesis, with high selectivity and catalytic activity.

-It can also be used as an electrochemical research reagent, such as in the application of lithium-ion batteries.

-Its good conductivity can also be used to prepare conductive polymer materials and electrolytes.

-Tetra-n-butylammonium perchlorate can also be used as an auxiliary propellant for rocket fuel and explosive

 

Main usages:

Used for the synthesis of  N,N-diethylethanamine,perchloric acid Cas no. 14999-75-8

Used for the synthesis of tetrabutylazanium,2,4,6-trinitrophenolate Cas no. 914-45-4

Used for the synthesis of triphenyl(triphenylgermyloxy)germane Cas no. 2181-40-0

Besides Safety Information ofTetrabutylammonium perchlorate  CAS NO.1923-70-2  is also important when handling it

 

Hazard Codes 

Xi

WGK Germany 

3

HSCode

2923 9000.90

TSCA 

Yes

HazardClass 

IRRITANT

 

 

What is the appearance of Tetrabutylammonium perchlorate  CAS NO.1923-70-2?   Please see the picture ofTetrabutylammonium perchlorate  CAS NO.1923-70-2, below

 

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Specification of Tetrabutylammonium perchlorate  CAS NO.1923-70-2, is below

Apperance: White crystalline solid, soluble in water and organic solvents

Assay: 99 min by GC

IR identity: conform

IR  picture of Tetrabutylammonium perchlorate  CAS NO.1923-70-2   is as follows,

 

H-NMR Spectrum  picture of  Tetrabutylammonium perchlorate  CAS NO.1923-70-2  is as follows,

Raman spectra of  Tetrabutylammonium perchlorate  CAS NO.1923-70-2  is as follows

Reference of  Article cited for your reference below,

(1)

Non-Fluorine Based Bulk Solution Techniques to Grow Superconducting YBa2Cu3O7−δ Films

Publication Date: 2005

Publication Name: Second-Generation HTS Conductors

(2)

Electrochemical Properties of Nanoparticle Assemblies

Publication Date: 2004

Publication Name: Self-Assembled Nanostructures

(3)

4.2.1.2.2.2.2 Neutral radicals

Publication Date: 1995

Publication Name: Carbon-Centered Radicals II