Tetraethylammonium hydroxide
What is Tetraethylammonium hydroxide, cas no:77-98-5,a producer telling you the result.
CAS NO.77-98-5
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To begin with, let us tell you what is the basic information of Tetraethylammonium hydroxide ?
Molecular Formula |
C8H21NO |
Molecular Weight |
147.258 |
Density |
1.023 g/mL at 25 °C |
Boiling Point |
110 °C |
Flash Point |
11 °C |
Melting Point |
-98ºC |
Like many stuff, it has many synonyms as follows
EINECS 201-073-3 |
tetraethyl-ammoniuhydroxide |
Tetraethylammoniumhydroxides |
Tetraethylazanium hydroxide |
TEA HYDROXIDE |
Tetraethylammonium h |
N,N,N-Triethylethanaminium hydroxide |
Tetraethylammonium hydroxide |
2K2&2&2 &&OH- |
First, the chemical is very special, some technical indexes as below
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Physical property data
1. Appearance: The product is a 20% aqueous solution and is a colorless or pale yellow liquid.
2. Density (g/mL, 25/4 ℃): 1.023
3. Relative vapor density (g/mL, air=1): uncertain
4. Melting point (º C): 40-50 ° C
5. Boiling point (º C, atmospheric pressure): 110 ° C
6. Boiling point (º C, 5.2kPa): uncertain
7. Refractive index: 1.4020
8. Flash point (º C): 11 ° C
9. Specific rotation (º):- 44° (c=11.2, H2O)
10. Spontaneous combustion point or ignition temperature (º C): uncertain
11. Vapor pressure (kPa, 25 º C): uncertain
12. Saturated vapor pressure (kPa, 60 º C): uncertain
13. Combustion heat (KJ/mol): uncertain
14. Critical temperature (º C): uncertain
15. Critical pressure (KPa): uncertain
16. Logarithmic value of oil-water (octanol/water) partition coefficient: uncertain
17. Explosion upper limit (%, V/V): uncertain
18. Lower explosive limit (%, V/V): uncertain
19. Solubility: soluble in water.
toxicology data
1. Acute toxicity
Subcutaneous LC50:107 mg/kg in mice;
Frog gastrointestinal LDLO: 60 mg/kg;
Ecological data
Currently unavailable
Molecular structure data
Currently unavailable
Calculate chemical data
1. Reference value for hydrophobic parameter calculation (XlogP): None
2. Number of hydrogen bond donors: 1
3. Number of hydrogen bond acceptors: 1
4. Number of rotatable chemical bonds: 4
5. Number of tautomers: None
6. Topological molecular polarity surface area 1
7. Number of heavy atoms: 10
8. Surface charge: 0
9. Complexity: 47.5
10. Number of isotopic atoms: 0
11. Determine the number of atomic stereocenters: 0
12. Uncertain number of atomic stereocenters: 0
13. Determine the number of chemical bond stereocenters: 0
14. Number of uncertain chemical bond stereocenters: 0
15. Number of covalent bond units: 2
Nature and stability
Corrosive.
Storage method
This product should be sealed and stored.
Second, the Synthetic Route we will recommend is the most important for your reference?
First, synthesis line of Tetraethylammonium hydroxide CAS NO.77-98-5 as follows
Main production methods:
1. First dissolve tetraethylammonium chloride in methanol, then add the theoretical amount of potassium hydroxide methanol solution, mix thoroughly, and potassium chloride will precipitate:
After the reaction is complete, let it stand and filter under reduced pressure. The filtrate obtained is added to water for reduced pressure distillation to remove alcohol and water, so that the content of tetraethylammonium hydroxide in the solution reaches 44%. Then, it is dried under vacuum, and the resulting crystals are the finished product.
2. First dissolve tetraethylammonium iodide in water to make it a 15% solution, then add the theoretical amount of silver oxide, heat in a water bath and keep warm to complete the reaction:
Other synthesie lines as follows,
Third, what is the usage of Tetraethylammonium hydroxide CAS NO.77-98-5 ? pleas see below
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Main usages:
1. Used as a chemical reagent and for acetylation of nucleosides.
2. Used as a polarographic analysis reagent to support electrolytes.
Besides Safety Information of Tetraethylammonium hydroxide CAS NO.77-98-5 is also important when handling it
Hazard Codes |
Xi |
WGK Germany |
3 |
H.S.Code: |
2923 9000.90 |
TSCA |
Yes |
HazardClass |
IRRITANT |
What is the appearance of Tetraethylammonium hydroxide CAS NO.77-98-5? Please see the picture of Tetraethylammonium hydroxide CAS NO.77-98-5, below
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Specification of Tetraethylammonium hydroxide CAS NO.77-98-5, is below
Apperance:colorless to lighy yellow liquid
Assay: 20% in H2O solution
IR identity: conform
IR picture of Tetraethylammonium hydroxide CAS NO.77-98-5 is as follows,
HNMR Spectrum picture of Tetraethylammonium hydroxide CAS NO.77-98-5 is as follows,
Roma Spectrum picture of Tetraethylammonium hydroxide CAS NO.77-98-5 is as follows,
Reference of Article cited for your reference below,
(1)
Recent Advancements of SAPO-34 and ZSM-5 Zeolite in Converting Methanol to Olefin: A Review
Publication Name: Arabian Journal for Science and Engineering
Publication Date: 2024-11-29
DOI: 10.1007/s13369-024-09786-w
(2)
Engineered nano-porous Cr₂O₃/TUD-1 nanocomposites for efficient and reliable humidity sensor
Publication Name: Applied Physics A
Publication Date: 2024-09-17
DOI: 10.1007/s00339-024-07899-5
(3)
Properties of quaternized and cross-linked hydroxyethylcellulose composite films
Publication Name: Cellulose
Publication Date: 2024-10-19