Tetraethylammonium hydroxide

四乙基氢氧化铵

What is Tetraethylammonium hydroxide, cas no:77-98-5,a producer telling you the result.

                                            CAS NO.77-98-5

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To begin with, let us tell you what is the basic information of Tetraethylammonium hydroxide ?

Molecular Formula

C8H21NO

Molecular Weight

147.258

Density

1.023 g/mL at 25 °C

Boiling Point

110 °C

Flash Point

11 °C

Melting Point

-98ºC

 

Like many stuff, it has many synonyms as follows

EINECS 201-073-3

MFCD00009024

tetraethyl-ammoniuhydroxide

Tetraethylammoniumhydroxides

Ethanaminium, N,N,N-triethyl-, hydroxide (1:1)

Tetraethylazanium hydroxide

TEA HYDROXIDE

Tetraethylammonium h

TENOH

N,N,N-Triethylethanaminium hydroxide

IPC-TEA-OH

Tetraethylammonium hydroxide

2K2&2&2 &&OH-

First, the chemical is very special, some technical indexes as below

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Physical property data

1. Appearance: The product is a 20% aqueous solution and is a colorless or pale yellow liquid.

2. Density (g/mL, 25/4 ): 1.023

3. Relative vapor density (g/mL, air=1): uncertain

4. Melting point (º C): 40-50 ° C

5. Boiling point (º C, atmospheric pressure): 110 ° C

6. Boiling point (º C, 5.2kPa): uncertain

7. Refractive index: 1.4020

8. Flash point (º C): 11 ° C

9. Specific rotation (º):- 44° (c=11.2, H2O)

10. Spontaneous combustion point or ignition temperature (º C): uncertain

11. Vapor pressure (kPa, 25 º C): uncertain

12. Saturated vapor pressure (kPa, 60 º C): uncertain

13. Combustion heat (KJ/mol): uncertain

14. Critical temperature (º C): uncertain

15. Critical pressure (KPa): uncertain

16. Logarithmic value of oil-water (octanol/water) partition coefficient: uncertain

17. Explosion upper limit (%, V/V): uncertain

18. Lower explosive limit (%, V/V): uncertain

19. Solubility: soluble in water.

toxicology data

1. Acute toxicity

Subcutaneous LC50:107 mg/kg in mice;

Frog gastrointestinal LDLO: 60 mg/kg;

Ecological data

Currently unavailable

Molecular structure data

Currently unavailable

Calculate chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): None

2. Number of hydrogen bond donors: 1

3. Number of hydrogen bond acceptors: 1

4. Number of rotatable chemical bonds: 4

5. Number of tautomers: None

6. Topological molecular polarity surface area 1

7. Number of heavy atoms: 10

8. Surface charge: 0

9. Complexity: 47.5

10. Number of isotopic atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 2

Nature and stability

Corrosive.

Storage method

This product should be sealed and stored.

 

Second, the Synthetic Route we will recommend is the most important for your reference?

First, synthesis line of Tetraethylammonium hydroxide CAS NO.77-98-5  as follows

Main production methods:

 

1. First dissolve tetraethylammonium chloride in methanol, then add the theoretical amount of potassium hydroxide methanol solution, mix thoroughly, and potassium chloride will precipitate:

 

After the reaction is complete, let it stand and filter under reduced pressure. The filtrate obtained is added to water for reduced pressure distillation to remove alcohol and water, so that the content of tetraethylammonium hydroxide in the solution reaches 44%. Then, it is dried under vacuum, and the resulting crystals are the finished product.


2. First dissolve tetraethylammonium iodide in water to make it a 15% solution, then add the theoretical amount of silver oxide, heat in a water bath and keep warm to complete the reaction:

 

Other synthesie lines as follows,

 

 

Third, what is the usage of  Tetraethylammonium hydroxide  CAS NO.77-98-5  pleas see below

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Main usages:

1. Used as a chemical reagent and for acetylation of nucleosides.

2. Used as a polarographic analysis reagent to support electrolytes.

 

Besides Safety Information of Tetraethylammonium hydroxide  CAS NO.77-98-5  is also important when handling it

 

Hazard Codes 

Xi

WGK Germany 

3

HSCode

2923 9000.90

TSCA 

Yes

HazardClass 

IRRITANT

 

 

What is the appearance of Tetraethylammonium hydroxide  CAS NO.77-98-5?   Please see the picture of Tetraethylammonium hydroxide  CAS NO.77-98-5, below

 

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Specification of Tetraethylammonium hydroxide  CAS NO.77-98-5, is below

Apperance:colorless to lighy yellow liquid

Assay: 20% in H2O solution

IR identity: conform

 

IR  picture of  Tetraethylammonium hydroxide  CAS NO.77-98-5   is as follows,

HNMR Spectrum  picture of  Tetraethylammonium hydroxide  CAS NO.77-98-5   is as follows,

Roma Spectrum  picture of  Tetraethylammonium hydroxide  CAS NO.77-98-5   is as follows,

Reference of  Article cited for your reference below,

(1)

Recent Advancements of SAPO-34 and ZSM-5 Zeolite in Converting Methanol to Olefin: A Review

Publication Name: Arabian Journal for Science and Engineering

Publication Date: 2024-11-29

DOI: 10.1007/s13369-024-09786-w

(2)

Engineered nano-porous Cr₂O₃/TUD-1 nanocomposites for efficient and reliable humidity sensor

Publication Name: Applied Physics A

Publication Date: 2024-09-17

DOI: 10.1007/s00339-024-07899-5

(3)

Properties of quaternized and cross-linked hydroxyethylcellulose composite films

Publication Name: Cellulose

Publication Date: 2024-10-19

DOI: 10.1007/s10570-024-06154-7