N-(1-Cyclohexen-1-yl)morpholine

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What is N-(1-Cyclohexen-1-yl)morpholine, cas no:670-80-4,a producer telling you the result.

                                                                           CAS NO.670-80-4

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To begin with, let us tell you what is the basic information of N-(1-Cyclohexen-1-yl)morpholine ?

Molecular Formula

C10H17NO

Molecular Weight

167.248

Density

1.0±0.1 g/cm3

Boiling Point

249.7±0.0 °C at 760 mmHg

Flash Point

68.3±0.0 °C

Exact Mass

167.131012

Like many stuff, it has many synonyms as follows

EINECS 211-579-6

MFCD00006163

Morpholine, 4-(1-cyclohexen-1-yl)-

4-(cyclohexen-1-yl)morpholine

4-(1-Cyclohexen-1-yl)morpholine

Morpholine, 4- (1-cyclohexen-1-yl)-

4-(Cyclohex-1-en-1-yl)morpholin

4-(1-Cyclohexenyl)morpholine

4-(Cyclohex-1-en-1-yl)morpholine

4-(cyclohex-1-enyl)morpholine

4-cyclohex-1-en-1-ylmorpholine

N-(1-Cyclohexenyl)morpholine

Morpholino-1-cyclohexene

First, the chemical is very special, some technical indexes as below

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Physical property data

1. Appearance: Colorless liquid.

2. Density (g/mL, 25/4 ): 0.995

3. Relative vapor density (g/mL, air=1): not determined

4. Melting point (º C): undetermined

5. Boiling point (º C, atmospheric pressure): undetermined

6. Boiling point (º C, 5.2kPa): undetermined

7. Refractive index: 1.514

8. Flash point (º C): 68

9. Specific rotation (º): not determined

10. Spontaneous combustion point or ignition temperature (º C): not determined

11. Vapor pressure (kPa, 25 º C): not determined

12. Saturated vapor pressure (kPa, 60 º C): not determined

13. Combustion heat (KJ/mol): undetermined

14. Critical temperature (º C): not determined

15. Critical pressure (KPa): undetermined

16. Logarithmic value of oil-water (octanol/water) partition coefficient: undetermined

17. Explosion upper limit (%, V/V): undetermined

18. Lower explosive limit (%, V/V): not determined

19. Solubility: Insoluble in water.

toxicology data

Currently unavailable

Ecological data

Do not allow undiluted or large quantities of products that are slightly harmful to water to come into contact with groundwater, waterways, or sewage systems. Do not discharge materials into the surrounding environment without government permission.

Molecular structure data

1. Molar refractive index: 48.93

2. Molar volume (m3/mol): 159.9

3. Waiting for Zhang Biarong (90.2K): 402.0

4. Surface tension (dyne/cm): 39.9

5. Dielectric constant:

6. Polarization distance (10-24cm3):

7. Polarization rate: 19.39

Calculate chemical data

1. Reference value for hydrophobic parameter calculation (XlogP): 1.7

2. Number of hydrogen bond donors: 0

3. Number of hydrogen bond acceptors: 2

4. Number of rotatable chemical bonds: 1

5. Number of tautomers: None

6. Topological molecular polarity surface area 12.5

7. Number of heavy atoms: 12

8. Surface charge: 0

9. Complexity: 171

10. Number of isotopic atoms: 0

11. Determine the number of atomic stereocenters: 0

12. Uncertain number of atomic stereocenters: 0

13. Determine the number of chemical bond stereocenters: 0

14. Number of uncertain chemical bond stereocenters: 0

15. Number of covalent bond units: 1

Nature and stability

Stay away from oxides and strong acids.

Storage method

Store in a sealed container and keep in a cool, dry place. The storage location must be kept away from oxidants.

 

Second, the Synthetic Route we will recommend is the most important for your reference?

There are multiple ways to prepare 1-methylmorpholine-1-cyclohexene, one commonly used method is to react cyclohexene with morpholine under alkaline conditions. Add cyclohexene and morpholine to the reactor and react under alkaline conditions for a period of time. Then, through appropriate purification steps, pure 1-morpholino-1-cyclohexene product can be obtained.

First, synthesis line of N-(1-Cyclohexen-1-yl)morpholine CAS NO.670-80-4  as follows

 

Third, what is the usage of  N-(1-Cyclohexen-1-yl)morpholine  CAS NO.670-80-4  pleas see below

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Usage:

1-morpholino-1-cyclohexene has various applications in the field of chemistry. It can be used as a solvent, as a catalyst and reducing agent in organic synthesis. It can also serve as a chemical reagent and intermediate, participating in various organic synthesis reactions.

Other usage:

Used for the synthesis of 2-Benzoylcyclohexanone, Cas no. 3580-38-9

Used for the synthesis of 2-Hydroxycyclohexanone, Cas no. 533-60-8

Used for the synthesis of methyl 1,1,3-trimethyl-7a-morpholino-3a,4,5,6,7,7a-hexahydro-1H-indene-2-carboxylate Cas no. 108790-85-8

 

 

Besides Safety Information of N-(1-Cyclohexen-1-yl)morpholine  CAS NO.670-80-4  is also important when handling it

 

 

Hazard Codes 

Xi

WGK Germany 

3

HSCode

2934999090

TSCA 

Yes

HazardClass 

IRRITANT

 

 

What is the appearance of N-(1-Cyclohexen-1-yl)morpholine  CAS NO.670-80-4?   Please see the picture of N-(1-Cyclohexen-1-yl)morpholine  CAS NO.670-80-4, below

 

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Specification of N-(1-Cyclohexen-1-yl)morpholine  CAS NO.670-80-4, is below

Apperance: Colorless to Light yellow to Light orange clear liquid.

Assay: 97 min by GC

IR identity: conform

Water:0.5% max by K.F.

 

IR  picture of  N-(1-Cyclohexen-1-yl)morpholine  CAS NO.670-80-4   is as follows,

Reference of  Article cited for your reference below,

(1)

Rhizobacteriome: Plant Growth-Promoting Traits and Its Functional Mechanism in Plant Growth, Development, and Defenses

Publication Name: Understanding the Microbiome Interactions in Agriculture and the Environment

Publication Date: 2022

DOI: 10.1007/978-981-19-3696-8_16

(2)

First Zinc Bromide Promoted Annulative Domino Reactions between Enamines and Cyclic Morita–Baylis–Hillman Alcohols: Synthesis of N,O-Ketals

Publication Name: Synlett

Publication Date: 2020-04-06

DOI: 10.1055/s-0040-1707467

(3)

Hydrogenation of Olefins, Alkynes, Allenes, and Arenes by Borane-Based Frustrated Lewis Pairs

Publication Name: Synthesis

Publication Date: 2021-12-22

DOI: 10.1055/a-1684-5552