Monomethyl maleate

What is Monomethyl maleate, cas no. 3052-50-4,a producer telling you the result.

 CAS NO. 3052-50-4

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To begin with, let us tell you what is the basic information of Monomethyl maleate CAS NO. 3052-50-4 ?

 

Flash Point

108.9±16.1 °C

Molecular Weight

130.099

Density

1.3±0.1 g/cm3

Boiling Point

250.0±23.0 °C at 760 mmHg

Molecular Formula

C5H6O4

MDL No.

MFCD00045905

 

 

Like many stuff, it has many synonyms as follows

EINECS 221-271-3

Maleic acid hydrogen 1-methyl ester

2-Butenedioic acid, monomethyl ester, (2E)-

(2Z)-4-Methoxy-4-oxobut-2-enoic acid

Maleic acid 1-hydrogen 4-methyl ester

MALEIC ACID MONOMETHYL ESTER

MMM

(2E)-4-Methoxy-4-oxo-2-butenoic acid

Maleic acid 1-methyl

(2Z)-4-Methoxy-4-oxo-2-butenoic acid

2-Butenedioic acid, monomethyl ester

Meleic acid monomethyl ester

methyl hydrogen but-2-enedioate

Monomethylmaleinate

MonoMethyl Maleate

Maleinsaeure-monomethylester

(2E)-4-Methoxy-4-oxobut-2-enoic acid

methyl hydrogen (2Z)-2-butendioate

Fumaric acid, monomethyl ester

methyl hydrogen maleate

MFCD00045905

2-Butenedioic acid, monomethyl ester, (2Z)-

 

The chemical is very special

 

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Ecological data

This substance may be harmful to the environment and special attention should be paid to water bodies.

Molecular structure data

1. Molar refractive index: 28.61

2. Molar volume (m3/mol): 102.7

3. Isometric volume (90.2K): 264.8

4. Surface tension (dyne/cm): 44.0

5. Polarization rate (10-24cm3): 11.34

 

Computational Chemistry Data

 

1. Reference value for hydrophobic parameter calculation (XlogP): 0.4

2. Number of hydrogen bond donors: 1

3. Number of hydrogen bond receptors: 4

4. Number of rotatable chemical bonds: 3

5. Topological molecular polarity surface area (TPSA): 63.6

6. Number of heavy atoms: 9

7. Surface charge: 0

8. Complexity: 147

9. Isotope atomic number: 0

10. Determine the number of atomic structure centers: 0

11. Uncertain number of atomic structure centers: 0

12. Determine the number of chemical bond stereocenters: 1

13. Uncertain number of chemical bond stereocenters: 0

14. Number of covalent bond units: 1

 

Properties and Stability

If used and stored according to regulations, it will not decompose.

Storage method

Sealed in a cool and dry environment at 2-8 º C

 

 

Second, the Synthetic Route we will recommend is the most important for your reference?

 

First, synthesis line of Monomethyl maleate CAS NO. 3052-50-4   as follows

 

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Third, what is the usage of  Monomethyl maleate CAS NO. 3052-50-4   pleas see below

 

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Chemical raw materials: Monomethyl maleate can be used as an intermediate in the preparation of polyester resins, solvents, coatings, inks, and other chemicals.

Alternative to ethyl formate: Due to its low solubility and vapor pressure, monomethyl maleate has relatively little impact on the environment and human health, and can therefore be used as a substitute for ethyl formate

 

Other usages as below

 

Can be used for the synthsis of the chemical, 2,4-bis(benzylamino)-4-oxobutanoic acid Cas No.: 25800-55-9

 

Can be used for the synthsis of the chemical, methyl 2-(3-oxo-4H-1,4-benzothiazin-2-yl)acetate, Cas No.: 7556-63-0

 

Can be used for the synthsis of the chemical, 2-(2-amino-4-oxo-1,3-thiazol-5-yl)acetic acid  Cas No.: 33176-41-9

Besides Safety Information of Monomethyl maleate CAS NO. 3052-50-4 is also important when handling it

 

Hazard Codes 

Xi

WGK Germany 

3

HSCode

2918 9900.90

TSCA 

Yes

HazardClass 

IRRITANT

 

 

What is the appearance of Monomethyl maleate CAS NO. 3052-50-4 ?   Please see the picture of Monomethyl maleate CAS NO. 3052-50-4, below

 

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Specification of Monomethyl maleate CAS NO. 3052-50-4, is below

Apperance: colorless to light orange clear liquid

Assay: 95 % min by GC

IR identity: conform

 

HNMR  picture of  Monomethyl maleate CAS NO. 3052-50-4  is as follows,

 

 

Reference of  Article cited for your reference below,

(1)

A cell-based, infectious-free, platform to identify inhibitors of lassa virus ribonucleoprotein (vRNP) activity

Publication Name: Antiviral Research

Publication Date: 2020-01

PMCID: PMC6954049

PMID: 31786250

DOI: 10.1016/j.antiviral.2019.104667

(2)

Direct Condensation of Carboxylic Acids with Alcohols: The Atom Economic Protocol Catalysed by Fe3+-Montmorillonite

Publication Date: 2002

Publication Name: Catalysis Letters

(3)

Enantiopure Cyclic Nitrones: A Useful Class of Building Blocks for Asymmetric Syntheses

DOI: 10.1055/s-2007-965914

Publication Date: 2007

Publication Name: Synthesis